Thứ Bảy, 27 tháng 10, 2018

Youtube daily report Oct 28 2018

 Roberto Firmino has been worth his weight in gold to Liverpool since arriving in a £29 million move from Hoffenheim back in June 2015

 Brendan Rodgers signed a lot of duds during his tenure at Anfield, but the Brazilian forward certainly wasn't one of them

 Firmino has been one of the most important players for Liverpool since Jurgen Klopp replaced Rodgers in October 2015

Without him, the team simply doesn't function nearly as well.  Unlike most strikers, Firmino isn't obsessed with scoring goals

He's a real team player who works tirelessly when he's on the pitch.  Former Liverpool striker Dirk Kuyt called Firmino the 'complete player' in April and it was hard to disagree with his assessment

 "He's a great goalscorer but he's also a team player in everything he does. I don't know him quite well, but if I see him playing he just wants to win with the team and he's not the type of player who wants to score for himself," Kuyt was quoted as saying by Goal

"That, for me, is the biggest thing about Firmino.  "He's scoring great goals but he's also giving great assists and then you are, in my eyes, a complete player, a great thing for Liverpool

 "I think he's also a very hard worker, he's selfless. I watch almost all the games and I see then he's always giving his all

Sometimes he's not scoring goals or giving assists, but he is always giving his all

" Firmino executes a no-look nutmeg v Cardiff  During his time at Liverpool, Firmino has scored a few audacious no-look goals

 But against Cardiff City, he managed to execute an incredible no-look nutmeg. Seriously

 Chased to the byline by Víctor Camarasa, Firmino has no choice but to improvise

And didn't he just.  Watch the video here…  Here it is in slow motion.  Now that's what you call cheeky

What a player.  Liverpool fans on social media all went crazy after the clip was posted online

Here are some of the best tweets…  No doubt kids up and down the country will be trying to execute the no-look nutmeg now

 Do YOU want to write for GiveMeSport? Get started today by signing-up and submitting an article HERE: https://www

givemesport.com/writeforgms

For more infomation >> Roberto Firmino pulled off a ridiculous skill v Cardiff City - fans can't get over it - Duration: 2:02.

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10 Signs You're Being Too Hard On Yourself - Duration: 4:39.

10 signs you're being too hard on yourself you probably don't realize that

you are putting too much pressure on yourself this happens frequently because

our world demands perfection that forces its people to push their limits

unfortunately this practice is not always good considering the fact that

people have different capacity in dealing with problems if you think you

have these behaviors you should consider stopping or slowing down a little bit in

this video I'm going to share with you some behaviors that reveal you're

putting too much pressure on yourself but before that please subscribe click

the bell and watch this video until the end to know the complete information 10

behaviors that reveal you're putting too much pressure on yourself number one you

are tired of trying after multiple trials you probably stopped trying or

struggling you feel so desperate because things are failing apart quickly and

there's nothing you can do anymore if this happens to you there's a chance

that you've put your best effort and pressure to yourself that you don't see

opportunities anymore number two you start looking back again

most people are really great in recalling history past experience and

bitter events this sets them back since they make people think unnecessary

things indeed past events can be the lesson however once is enough and being

stuck there is not an option of relaxed people number three you think you are

bad people who are not forced will not feel good at all in fact they feel

burdened and they don't feel like life is fair when this happens desperations

follow and you eventually force yourself too hard to achieve something that is

impossible to be achieved number four you don't love yourself when

you think you are bad you start blaming yourself you start hating yourself for

not being capable or unskilled you also curse yourself to death because it seems

like everything is fighting against you when this happens

you actually put too much constraint in yourself and you will not gain anything

in the end number five your life is full of negativity if you feel like you are

going into a creative ways or when you feel like your life doesn't go anywhere

enjoyable and it just come to you there is probably something wrong one thing to

blame is that you work too hard that you don't enjoy the process anymore if this

happens you will only think the negative not the positives like usual number six

you always feel depressed what is the more obvious sign compared to feeling

and looking depressed it is very easy to pick up the desperation from others and

if others tell you so there's a problem with you there's a high chance that you

feel so because of forcing yourself to expectation that you cannot meet number

seven overthinking another great sign that you may experience when attacked by

extreme pressure is overthinking now you become extremely skeptical and you

overthink everything it's like you are afraid of making mistakes and

unfortunately it makes you perform less than desired number eight unrealistic

expectation yes expectation is the greatest turtles that

you possibly cannot face it is unfortunate but it is important for

people to keep everything realistic number nine you are not easily satisfied

you always want more and more you always want to be better than your currently

are you always want something greater for you though it is really good to have

expectation you should be grateful and satisfied sometime otherwise you are in

the loop of endless satisfaction pursuit number ten you don't take a break it is

always suggested that you stop for a while to enjoy what you've earned or

create it take some time a week or so to reflect and enjoy otherwise you are

forcing yourself to take what you cannot take well those are the ten behaviors

that reveal you're putting too much pressure on yourself so really cool

information isn't it I hope you enjoyed this short video if you have something

on your mind please share your thoughts and

experiences in the comments below don't forget to subscribe to our channel

and watch all our other amazing videos

you

For more infomation >> 10 Signs You're Being Too Hard On Yourself - Duration: 4:39.

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ОНА ВСЕ ИСПОРТИЛА! 우리 망했어요 ㅠ [KOR SUB] - Duration: 15:00.

For more infomation >> ОНА ВСЕ ИСПОРТИЛА! 우리 망했어요 ㅠ [KOR SUB] - Duration: 15:00.

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錦織2年8カ月ぶりVへ今度こそ"9度目の正直"だ - Duration: 3:56.

For more infomation >> 錦織2年8カ月ぶりVへ今度こそ"9度目の正直"だ - Duration: 3:56.

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Amber Alert For Woman And Child - Duration: 0:35.

For more infomation >> Amber Alert For Woman And Child - Duration: 0:35.

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Life Lessons From Goddess Kali - Duration: 7:08.

For more infomation >> Life Lessons From Goddess Kali - Duration: 7:08.

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REMEMBER WHEN... Rough Seas ► All 4 Adventure TV - Duration: 1:13.

How good is it going out in the big boat?

All time.

Look, it's good when it's clear, and we've got the clear blue skies and the calm waters.

But it's not always like that.

This is going to be a bone-jarring 3 hours ahead of us.

The 5-metre groundswell predicted isn't a problem, as the distance between the waves is huge.

The chop on top is what is giving us the grief.

On the way out, the crew pass overhead.

And as you can see, it's a lonely old ocean out there.

How messed up was that trip?

Mate, the ocean was just a mess. It was puss.

Jackin' up.

Now Simon has a novel seat in rough water on the motor.

He reckons it's the smoothest spot on the boat.

Personally, I think he just enjoys it.

It's a bit rough.

Ten years of All 4 Adventure. I can't believe it.

Mate, that is a Decade of Dirt.

For more infomation >> REMEMBER WHEN... Rough Seas ► All 4 Adventure TV - Duration: 1:13.

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Ash PUMPS Misty's BUTT?! (Secrets Revealed!) - Duration: 25:18.

hello how are you guys doing today my name is black Tarzan and today I'm super

excited to bring you this brand new video of ash pumping Misty's but I know

what you guys are thinking Wow does Ashley really pump Misty's but it

like can you show this on YouTube yeah I can and if you guys want to see it you

all you have to do is just follow the four steps that I'm about to tell you

and you will be able to see this amazing clip because you know YouTube lets me

program the YouTube algorithm lets me program all my videos to not show you

certain video footage unless you do what I say it's a feature only available to

those people who have like really high amounts of subscribers you know I have

like 87 thousand subscribers so obviously it lets me do it

so yeah so to be able to see ash pumping Misty's but all you have to do is number

one you have to be subscribed with notifications turned on number two you

have to like or dislike this video number three you have to just leave me a

comment and then number four you have to share the video I'm gonna be listing all

the instructions down below in the description if you guys can't hear me

very well or I'll leave it in the I'll also leave

a comment just in case you know you guys get really lost so yeah go ahead do all

those steps subscribe the notification is turned on be sure to like this video

leave a comment and share this video and you will be able to see Ash and Misty

having some smoky time so definitely be sure to do that anyway let's get right

into the video let's go

okay so before I show you guys the clip of Ash and Misty you know of ash pump

and Misty's but let's first talk about misty because we have to understand the

important story that goes behind this now misty first appeared in like the

first or second episode of Pokemon you know we saw her she was like ash Ash's

Pikachu was hurt and Ash had some problems and he needed some help so you

know misty had a bike and ash was like don't miss can I get you a bike and

misty was like no but ash was it you know he's a straight-up thug he doesn't

care about nothing so he just went in a few collab Misty's

bike he just sped away with it I mean this is like it's crazy I mean like

people in the hood do this all the time but ash is about a straight-up you know

just go to light a poor innocent girl who can't even defend herself and

literally still it was bike I mean a lot of people just thought oh it's a cartoon

but you know I should have been more you know responsible he maybe should have

asked for permission or rented it you can't just go up to someone and just

like legit just like taking steal their bike like that's kind of messed up but

yeah you know ash he just you know I'm saying he just went up and he took her

by anyway so after that he speeds into the the forest and you guys know what

happens I mean you can watch the second episode of Pokemon I'm not gonna go over

most of you are younger though I mean I'll tell you there's this term called

Gen one or like I'm a gen Warner it's like you you y'all kids need to go out

there and you'll need a watch the first season a Pokemon if you haven't because

it's really good I think it's I mean I like the new ones too

get me wrong that the old ones also have a special thing to it I think a lot of

people take the old Pokemon episodes for granted but those were hyped to guys

like not gonna lie anyway so we don't see misty for a long time and then you

know later up in a couple of episodes ash nice Missy again and she's like yo

can I have my bike back ash is like yo I'm sorry your bike got trashed like I

don't know what to tell you mr. like your buddy got crashed I you know burned

it and I don't have the money to pay you back and so misty was like alright then

you know you don't have the money to pay me back I'm gonna have to follow you and

be your companion and go everywhere with you and don't second-guess these guys

you know it's it's October over here so it's kneading season

I'm not sick and just just needed I mean I'm just blowing my nose all right

anyway so it's kind of weird she's like well if you don't have the money for my

bike I'll just follow you around and we can just do stuff together and you know

a lot of slow curious because they're like two young people and they're

traveling around the world together so I mean one has to wonder what goes on

after hours you don't like what happens and so that's why I made this video to

show you because the creators of Pokemon just released this new footage of Ash

and Misty just going at it so remember guys if you want to see this clip you

got a number one subscribe and because I'm about to show it right now so the

final warning is number one you need to be subscribed to the black Tarzan

channel but the notifications turned on number two you need to either like or

dislike this video number three you need to leave a comment and before you need

to

what do you need to do

number four you need to share this video

now some of you guys on the last video we're having some technical difficulties

and I am going to tell you that if it doesn't work with the first account now

some of you are mobile some of you are on a laptop or a desktop or a tablet or

whatever Kindle or Kindle Fire or whatever anyway what's going on is if

you're on mobile because most people use mobile and it doesn't work for you

create a new account or use like your mom your sister your brother whatever is

account sign in subscribe and do all the steps and then refit but like close and

open the video and restart the app or a browser or whatever and it should work

for your computer you know restart your browser try with a different account and

it should work there's no reason it shouldn't work a lot of people who are

just saying that in the comments are really literally just trolling there's a

lot of trolls on my channel but it will work for you so just keep subscribing

make new accounts or whatever and yet you should be able to see it because I'm

not just gonna give it I'm not just gonna show you this content free because

you know I worked hard to find this I had to contact a lot of like Pokemon

officials and secret you know Pokemon agents so I'm not just gonna release it

to you guys for like nothing I mean that doesn't make no sense so go ahead and

I'll people probably provide a technical support in the comments so let me know

anyway

yeah anyway you know I think Ash and Misty are going to have a very

successful future together I mean I do end up seeing ash proposing

to misty and then getting getting married you know it's a possibility that

could happen so don't think I mean in my opinion some people say like he might be

with another female in Pokemon anime but I mean there's some good competition I

mean you got Serena which the story people people made Pokemon literally

change the whole story they put her back in his childhood

just to like introduce Serena so Serena's like the huge competition and

right now 50/50 split I really don't know is it going to be missed you or is

there gonna be sore arena or is it gonna be may I I don't think it's gonna be me

it could be it could be there's some I've been poking some strings here I did

make a video about hash in May I made a video about all the pokemon female urges

but I did make a video about ash in May so it could happen guys leave me a

comment below like saying who you think ash is gonna end up with because it's

very hard to protect us in the future but Misty is like one of those special

characters because they brought her back I need ash and miss you were super

friends and they brought her back to the new Aloha series Pokemon anime so what

does that tell you I mean that tells you that misty was a huge and super

important character in the anime that they were gonna even bring her back as a

new special character they didn't even do that - Serena forget sir they didn't

really do it

yeah guys just I literally I just woke up I was like I'm gonna make this video

because a lot of people need to see this new leaked footage so that's why I kind

of wait for Bellefleur it's literally

it's like 9 a.m. I woke up like 2 hours ago

I'm starting to get better with my sleep patterns and I'm starting to take care

of myself and actually go to sleep on time so that's the best plus I really

don't know what else I should say on this video I mean I've gone through a

lot of other things yeah

testing

shit

all right so let's go over misty

misty is a character whose first appearance was in the very first episode

of the anime series in the first episode she first meets ash after fishing out of

the water when she was trying to get away from the Frank espero ashlynn takes

Misty's bike from her in order to escape the sparrow which is then wrecked by

pikachu thunder shirt misty then tracks down ash and all his adventures

until he can pay her back up although she eventually forgets about the body

and becomes one of Ash's closest friends in the process however at the end of

their journey through Johto region Misty's bike has been fully repaired as

she departs to return home to swimming suit to assume her duties at agenda

she's currently a Cerulean City junior after the older sisters

testy

Oh

misty has short hair orange hair tied into a side ponytail she has green eyes

and fair skin she wears a yellow tank top that shows her midriff red

suspenders blue denim shorts that stop her at her thighs and red sneakers with

yellow lining and white laces her whole midriff is showing but her bellybutton

is usually not grown on however it is visible when she is in her two-piece

swimsuit in Sun moon she later maintains her original outfit

in her return to Pokemon series Sun and Moon beneath her outfit is her strapless

two-piece swimsuit which is worn by her counterpart in both games pokémon red

and blue in SM 43 when Regents collide misty has a key stone hidden at the back

of her ponytail in one episode in pokémon chronicles her primaries hop is

replaced with a yellow sleeveless hoodie shirt but maintains her denim shorts

with her sneakers from her primary outfit and color of her denim shorts

were purple her new outfit at the advanced

generation series when she meets up with ash and Brock and Hoenn consists of

yellow sleeveless vest with a dark blue but the dark blue collar red swimsuit

yellow shorts and whorin shoes personality misty has a slight

inferiority complex mostly due to the three older sister Daisy the oldest

violet second from oldest and Lily third from

oldest who formed the group the three sensational sisters their synchronized

swimming group and refers to misty as the run or the weaker one

this complex the mitten diminishes over time as misty grows closer to them until

misty

resumes her duties at the cerulean sea gym leader her sisters were the ones who

directly ran the gym although Ashe although when ash came

along to get his cascade batch it was misty who battled him pour it explicitly

referring to herself as being one of the gym leaders during this instance misty

specializes mainly in water type Pokemon which are her favourite type but she's

had other types and she also deeply admires Laurel Laurel a as a ice type

pokemon trainer misty aims to become a world-class pokemon trainer and her well

trained pokemon reflects her aspirations of becoming so her least favorites have

a pokemon is the butt type pokemon a deep

as she is

now she has a deep-rooted fear of them except for the kind she sees as cute or

pretty however misty Misty's fear lessons over

the course of the series but is not to the point where she's totally gotten

over it as shown in a real cleffa anger as your series continues she gradually

shows herself to be kind and sensible sometimes she would restrain Brock from

girls off and pummel him away from that by the ear recommending him for his

behavior this trait continued with hit with the

friends who join ash on his journeys after she parted ways with him following

their journey through the johto reason misty is a great Fisher making good at

making lures for her fishing and an amazing battler due to being a gym

leader biography

misty can be very nice to her friends but will then quickly change moods in a

short amount of time particularly anger she is quite proficient in anything

having to do with water type with water as she can be seen in certain episodes

where she has the ability in fishing swimming an overall water type Pokemon

training even though she wanted to stay with ash misty felt obligated to watch

over the gym since her sisters would be gone on their world trip the two went

their separate ways and Misty resumed her duties as gym leader at Cerulean

City Gym advance generation series in this series misty wears a pale yellow

vest sleeveless jacket and a dark blue button and a collar of the same color

she wears yellow shorts a Princeton leotard under her vest and a burnt

orange high tops and white socks Missy only appeared as a guest star and

the remainder of the Pokemon series in one of her cameo appearances the indie

advanced generation series her togepi evolves into toget togetic mister

releases togetic after it chooses to stay behind to defend the mirage kingdom

and Togepi paradise

after ash finish finishes competing in the Hoenn league he returns home to

Pallet Town to find misty waiting for and however she isn't

the only one to rejoin ash May Max and Brock join him as well for the battle

frontier challenges she travels with the passion for two episodes and then

returns to her gym shortly afterwards misty returns alongside with Barak in

sm0 42 when ash returns to cancel after his travels in a low on for his school

project of his classmates she is one of the special guests along with Brock who

is one it is the one who pinched Brock's ear to meet up with him ash holding him

after the exploration she is the only one who releases a loli in Pokemon

compared to Kanto Pokemon and helping Lana to find her PO polio under the

depths of the lake she stays ELISA stars each a Brock's as crobat and Ash's like

an rock to rescue their friends Pokemon from Team Rocket the next day they

traveled to Cerulean City for extra curricular lessons and after Brock tells

ash about his younger brother Forrest who currently runs the patch where city

gym miss he tells them her sisters are travelling much to Brock's depression

in sm0 43 misty shows to them the inside of the newly rebuilt

Cerulean City Gym and became thankful for her Psyduck

to guard the gym she also uses this to battle against malos tini and Lena

Lana's papi Leo in a handicap but when Saida gets with a severe headache and to

unleashed confusion on both pokemon misty calms it despite it it hurts

its head misty later battles ash against using this website is so hard to read on

I apologize guys what does it say

she also reveals key stone hidden at the back of her hair clip of her ponytail as

she mega evolves her diary dos despite her strategy her mega guru dose

was defeated by Pikachu who uses the Z move the gigavolt hot - after giving

Lina Malo and Lily some Cascade badges she and Bronk will told by ash to visit

him at a low low which they agreed before ash and others depart misty

became interested in Ash's earring as she admits that she teases ash making

them laugh oh man that's cool Oh should we go through the trivia yeah

why not why not go clear trivia guys

by some trivia guys Missy is the first victim of a reoccurring gag in the enemy

where Ash's Pikachu destroys every main female characters bike this gag was also

transferred to Mei and Dawn however this gag did not affect iris

Bonnie or Serena because they did not have buns iris and Bonnie were shocked

directly by Pikachu while Serena wasn't shocked at all

all right that's pretty much it for today guys I really don't have any more

information about misty at this time I hope you guys enjoyed watching the video

thank you guys so much for watching my name is black Tarzan thank you guys so

much for watching I really appreciate it peace boots

oops

For more infomation >> Ash PUMPS Misty's BUTT?! (Secrets Revealed!) - Duration: 25:18.

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Tigres 2-2 Lobos BUAP – GOLES – RESUMEN – LIGA MX – DECIMOCUARTA FECHA - Duration: 1:26.

For more infomation >> Tigres 2-2 Lobos BUAP – GOLES – RESUMEN – LIGA MX – DECIMOCUARTA FECHA - Duration: 1:26.

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Lab Notes: Terpin Hydrate failures, Urushibara Nickel failure, and Additional Sodium Work - Oct 28th - Duration: 12:35.

Greetings fellow nerds.

This week there is very little sodium work, as i'm waiting for more chemicals to arrive in the mail.

I also landed a new job.

So things have been hectic as i settle in so my videos are going to come out less often but once i have a good routine going i should be returning to normal video production.

Now in other channel news i have received another community guidelines strike on my channel.

This time against my synthesis of sodium cyanide video.

And to be honest, this is the first strike i actually accept.

Now i personally think the educational value outweighs the danger.

But i can see it from their point of view why they wouldn't like it and removing it isn't contradictory to the policies of youtube.

Nor is the reason excessively broad like when they took down my synthesis of the antimalarial drug pyrimethamine.

So i'm not going to fight this particular strike.

I suppose after indiscriminately taking down so many videos, they had to find a valid one eventually.

But since my channel is closer to being banned, i do hope i last long enough to produce my last great project, the sodium synthesis.

Now i as said before i'm still working hard on it and progress has been steady.

In particular i'm trying to get more catalysts for my sodium experiments.

Buying them through the mail is one option, but as i wait i wanted to try making some.

Now one catalyst candidate that's been suggested to me a lot is something called terpin hydrate.

It's based off of 4-terpineol and is actually the product of hydrating the double bond.

The original alcohol group undergoes a migration by passing through an alkene intermediate.

What we essentially get is two tertiary alcohols on one molecule.

Now i'm not sure if this would do us any good, and it might make the resulting alkoxide too polar to be soluble but we might as well give it a shot.

Now i looked for literature on how to make it and it seemed simple enough,

mix a source of terpinenes like tea tree oil or turpentine with dilute sulfuric acid and stir for a prolonged period.

So i did that, i mixed about 200mL of tea tree oil with 200mL of water and added 30g of sulfuric acid and then stirred.

The literature says this should yield a precipitate of terpin hydrate overnight.

Then i stirred for about three days and at the end of it, nothing happened.

I then left the mixture in the back of my fume hood for three weeks and finally a tiny clouding of stuff seems to be coming out.

It's not very much though.

I'm not even sure if we could recover that.

Now some literature sources suggest high concentrations of acid so i tried again with 50mL of tea tree oil, 20mL of water, and 50g of sulfuric acid.

Looks like we're getting some reaction.

But even after a few days I wasn't seeing anything solid.

At this point i kinda abandoned this line of inquiry.

Not because it can't work, i'm sure i'm probably doing something wrong.

But i think my efforts are best spent on more promising avenues like finding an off-the-shelf catalyst.

I may yet revisit terpin hydrate as a catalyst if everything else doesn't pan out.

I'm still leaving this flask in the back of the fume hood in the hopes the reaction continues.

Anyway, as found in a previous lab notes video.

4-terpineol from tea tree oil was found to be a workable catalyst, but decomposes with time so a large starting amount is necessary.

4-terpineol also needs to be isolated from tea tree oil by fractional distillation, which is not all that easy at the temperatures required.

Now a way to solve both problems is to hydrogenate tea tree oil.

This is already well-known chemistry.

Basically add hydrogen to the double bond and hopefully make the resulting alcohol resistant to decomposition.

This would also make all olefinic impurities aliphatic which should be as inert as the mineral oil we're using to run our reactions.

Unfortunately this does not happen by itself.

If you feed hydrogen into an alkene, nothing happens.

So we need a catalyst.

The most common catalyst in the laboratory is palladium on carbon.

If you want actually see palladium on carbon being used for hydrogenation then i recommend checking out Applied Science and NileRed,

both of those channels perform hydrogenation of vegetable oil to make margarine.

They're excellent videos and i've linked them in the video description.

Now palladium on carbon is within the abilities of the amateur to make but like making tertiary alcohols,

it's a rather involved process and you also need to buy palladium.

The effectiveness makes it cheap since you can use very little, but the initial cost might be prohibitive.

So to make my hydrogenations more amateur friendly, i decided to try and make another catalyst called urushibara nickel.

It's not as effective as palladium, but the required chemicals aren't too hard to get.

First i had to make nickel chloride.

Nickel chloride can be purchased online but nickel metal itself is often easier to get.

You can even hack it out of nickel metal hydride batteries and it will work.

So to convert nickel metal to nickel chloride i added it to hydrochloric acid.

But nickel reacts very slowly at room temperature so to speed it up it needs to be boiled.

Eventually this forms nickel chloride.

I made a lot of it since i wanted to do other experiments with nickel and I don't have nickel chloride as a stock reagent.

I then boiled it dry and eventually obtained nickel chloride.

Now making urushibara nickel precursor isn't that hard.

Zinc powder is obtained and a one tenth mass equivalent of nickel metal is weighed out in the form of a nickel salt.

Like our nickel chloride from earlier.

We then add water to both and heat them up until they boil.

From what i read in the literature the more vigorous the reaction the better the resulting catalyst, and thus why we're boiling everything.

Now looking back at this point i think i screwed up.

If you look over at the zinc it seems be rather pasty.

I don't think that's zinc, i think it's more zinc oxide.

The zinc powder i was using must have oxidized over the years over to zinc oxide.

What i should have done before i started was wash the zinc with dilute sulfuric acid.

Zinc oxide easily dissolves in sulfuric acid but zinc metal actually dissolves very slowly because it has high hydrogen overpotential.

Unfortunately i didn't think of that in time, so i went on to the next step.

Mixing the boiling nickel chloride solution directly into the boiling zinc paste.

Now this extremely vigorous reaction is actually perfectly normal.

We're getting a very exothermic metal displacement reaction with the nickel depositing very fine particles onto the zinc.

It's so exothermic that it's boiling the mixture further.

So my crappy zinc still has enough good zinc in it to make this reaction work.

Although i still think i would have been better off using good zinc.

Anyway looking back i should also have used a bigger flask to contain the reaction.

Luckily I had the foresight to install a splash arrestor on the flask before i started to deal with exactly this sort of occurrence.

As you can see i definitely got my money's worth here.

Anyway, I let the reaction continue until it stops.

Next we filter our mixture to get our precursor.

Be sure it wash it with lots of water and finally with some methanol to get rid of all the leftover salts.

And here it is after drying.

Yeah i really think i have way too much zinc oxide.

Hopefully i get some activity out of this but if i don't, i know what to fix.

Anyway, this is the Urushibara nickel precursor.

Basically it's ultrafine nickel deposited on zinc particles.

In this form it's stable indefinitely but not directly useable.

To make it useable for hydrogenation it's reacted with a strong base or weak acid to destroy the remaining zinc and release the nickel particles.

Then those particles are filtered and used for hydrogenation.

But that's best done just before you actually do perform your hydrogenation.

The activated nickel loses activity as it's exposed to air, so it's best kept in this precursor state when you're not using it.

Anyway i'm still preparing for the hydrogenation so i'll get to that eventually.

But as you can see, overall, the process for making the catalyst doesn't seem to be that hard.

If this works as is i'll make a proper video with masses and variables, and if not i'll try again.

Now i've been running a concurrent sodium experiment where i ran with an excess stoichiometric ratio of sodium hydroxide to magnesium.

If you recall i already ran this test awhile back to see if we could avoid using dioxane by making sodium without magnesium contamination.

We found that it was very difficult to finish since the reaction just kept getting slower and slower and even after three days it never finished.

While i decided to revisit that experiment since i had more time now and this time I used huge amounts of sodium hydroxide, almost twice as much and i ran for several days.

Finally the reaction flipped over and all the magnesium was consumed but something interesting happened, the sodium broke up into a very fine dispersion.

You can see it here almost like sand.

Let me see if I can get closer and get a macro shot, and there we go.

It's clearly a spherical metal so it's not the original magnesium just worn down.

When i poured it out most of the slurry passed through the sieve and whatever did collect was very little.

So it seems like a little bit of magnesium is needed to keep the sodium metal together in large globules.

I actually noticed this effect very early in my experimentation but i wasn't certain it was due to excess sodium hydroxide as i was also dealing with glassware destruction at the time.

So I had to consider the possibility it was a glassware contamination problem.

But now it looks like it really is an effect of using excess sodium and letting the magnesium be consumed.

Now you might be wondering how does magnesium prevent the sodium from breaking up.

What i think is happening is the magnesium is imparting a negative charge to the sodium as the magnesium is oxidized by the reaction conditions.

This charge alters the surface tension of the sodium and either allows the sodium to easily coalesce with other droplets of sodium or makes it harder for the sodium to detach and break up.

Perhapes both effects are at work.

We've actually seen a very similar effect way back in the gallium beating heart experiments.

In those experiments the gallium metal changes its surface chemistry in a sulfuric acid solution whenever it's left on its own or when when it touches an iron wire.

In this case we have sodium metal for gallium metal, and magnesium metal for iron.

Bottom line, in order for us to get great sodium coalescence under these reaction conditions we need a small amount of magnesium to maintain the right surface charge on the sodium.

So it looks like we'll always need to run with excess magnesium.

First, because the reaction becomes terribly slow if we don't.

And second, and perhaps the more important reason, because the magnesium maintains sodium cohesion.

You might be thinking that we can use dioxane to recover the sodium droplets from this slurry.

While that might be possible it only underscores the continued need for dioxane.

If we're going to keep using dioxane then we might as well keep with our current methods of using dioxane to separate sodium from magnesium metal.

You know, looking back, i remember lots of amateurs running with excess sodium or potassium hydroxides

when they were doing their experiments since magnesium was the more expensive reagent.

Perhapes a lot of their reaction failures weren't failures at all, but simply loss of product because it was this fine dispersion.

They did report that the resulting slurry was exceptionally reactive, but couldn't collect any large pieces of sodium or potassium metal.

Now that we know product cohesion is dependent on excess magnesium this might offer an explanation.

So you amateurs that were working on this research years ago and kept failing but got highly reactive slurries.

Perhaps you did succeed and didn't know it.

So that's what i've been up to for now as i wait for more chemicals to arrive.

Hopefully they'll get here soon and i can start testing, but if not i'll get to work on hydrogenation of tea tree oil.

Thanks for watching.

At this point i'd like to thank my patreon supporters.

I would never have bothered to research anything this thoroughly or produce lab notes without your approval.

It's because of you that we have come this far, thanks

For more infomation >> Lab Notes: Terpin Hydrate failures, Urushibara Nickel failure, and Additional Sodium Work - Oct 28th - Duration: 12:35.

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錦織2年8カ月ぶりV王手!決勝は8位アンダーソン? - Duration: 3:10.

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Large Pallet Fire Burning In City of Industry - Duration: 1:08.

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WATCH LIVE: Prep Sports Extra for Saturday. October 27, 2018 - Duration: 37:30.

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她是邓伦娱乐圈的启蒙老师,促成与杨紫合作,今新作即将见面 - Duration: 4:23.

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Trades to weaken tomorrow, shifting to Southerly winds - Duration: 2:39.

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VIDEO - OSU beats Texas on homecoming - Duration: 3:09.

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海贼王:这5个垃圾到爆的果实,硬是被开发出神级威力!秒杀明哥 - Duration: 12:36.

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Saturday night high school football highlights: October 27, 2018 - Duration: 1:04.

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<フィギュアスケート:スケートカナダ> 宇野昌磨が2連覇、逆転VでGPファイナルに前進? - Duration: 4:12.

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双世宠妃2:真正曲小檀归来,与曲檀儿上演夺夫之战,结局太虐心 - Duration: 3:52.

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MatiK - Psy chodzące w maskach klaunów (Prod. Tower B./L.E.M. Beats) - Duration: 3:09.

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35歲苟芸慧嫁豪門,信用卡無上限,收人錢財要生B,承諾40歲生4個! - Duration: 3:15.

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ОНА ВСЕ ИСПОРТИЛА! 우리 망했어요 ㅠ [KOR SUB] - Duration: 15:00.

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杨紫终于表白张一山,张一山回应5个字,网友:真该打 - Duration: 2:29.

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How To Clean a Derma Roller After Use - Duration: 2:10.

In today's video I'm going to be showing you how to clean your derma roller at home. It's an important step

So let's get stuck into it

Hey guys

I'm Storm Watson, founder of the skin educator and every single week I bring you skin videos that are going to help you

Heal your skin conditions and maintain healthy clear skin

So be sure to subscribe and hit the bell to be notified

when I upload each Sunday. Dermal Rolling is an amazing treatment you can do in the comfort of your own home if you're after a

Tutorial on how to use a derma roller at home then make sure to check out my video from last week

I'll pop that in the description below for you guys to watch after this video, but in today's video

I'm actually going to be showing you how to clean your derma rollers at home

Sometimes we do get irritation on the skin and if you are using a derma roller

That could actually be the cause if you're not cleaning it

So it's really important to clean it two to three times a week and in this video

I'm going to be showing you how

So what I do to clean my derma roller at home is I use some warm water

some tea tree as it's antiseptic and anti bacterial and I mix these together. Then I'll use a toothbrush not used and

Just wipe over the roller with a diluted tea tree. Now. This is super easy and affordable and it'll keep your roller

really clean

You can swish it through if you need to and just leave it to dry overnight

If you're applying the serums first to the skin before derma rolling, then it's so important that your roller is clean

So clean this twice a week and by cleaning your roller, it will prevent any irritation happening on your skin

So now you guys know how to clean your derma roller at home

Make sure to comment down below if you're going to be doing this at home

It's so affordable! If you guys are wondering what serums to use with your derma roller

I do have an active ingredient guide that might be great for you, just download that one down below

And I'll also explain what kind of serums would be best for your skin condition

If you guys liked this video

Please make sure to give it a like, subscribe and share with your friends, and I will see you guys in my next video. Bye

For more infomation >> How To Clean a Derma Roller After Use - Duration: 2:10.

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陸毅演藝道路三十年 - Duration: 36:55.

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Croquis Cafe: Figure Drawing Resource No. 342 - Duration: 22:27.

Hi, I'm Larry Withers and welcome back to the Croquis Cafe.

Well, as promised, this week, in addition to our regular model...

We're posting a new Croquis Cafe SketchPad video on the topic: Is artistic anatomy really necessary?

To see that video follow the link below.

Please, follow us on Instagram, and post your drawing to Instagram: #croquiscafe.

We appreciate all of you who've donated to the Croquis Cafe.

Large or small, all donations are appreciated.

To support the Croquis Cafe, follow the link below to our donations page.

And with that we bring you this week's Croquis Cafe.

We hope you enjoyed this drawing session. To continue drawing from our model, Keira Leilani...

Click on the video below to see her previous drawing session.

Or select our playlist to see hundreds of other Croquis Cafe videos.

Subscribe to our channel and please don't forget to donate to the Croquis Cafe.

For more infomation >> Croquis Cafe: Figure Drawing Resource No. 342 - Duration: 22:27.

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For more infomation >> Croquis Cafe: Figure Drawing Resource No. 342 - Duration: 22:27.

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[Live] Nắng Ấm Xa Dần (Onionn Remix) | Sơn Tùng M-TP | Tại Event FWD Music Fest | 27/10/2018 - Duration: 3:18.

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For more infomation >> [Live] Nắng Ấm Xa Dần (Onionn Remix) | Sơn Tùng M-TP | Tại Event FWD Music Fest | 27/10/2018 - Duration: 3:18.

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You My Love The Latter - Duration: 4:39.

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Gainful - Personalized Protein

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The end |Jose Garcia - Duration: 3:02.

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YOUNG AVENGERS ?? Top 5 Famous Superheroes Turned Out To Be LGBT - Duration: 6:51.

MovieDay OmLamis

The rise of discussion about LGBT in Indonesia made me wonder

Are there fictional characters like superheroes who also have LGBT?

The fact is, there is

Behind the figure of every super-strong hero who is famous

authoritative, handsome, beautiful and helpful

apparently some of them are LGBT people

The following is "5 superheroes who turned out to be LGBT"

Wiccan

Wiccan is a super hero and is a member of Young Avengers

a team of superheroes whose members are on average teenagers

Like the Avengers

Young Avengers also has the duty to protect and protect humans from enemy threats

Wiccan has the real name William "Billy" Kaplan

a mutant from an old man who is also a super hero

Scarlet Witch and Vision

At a glance Wiccan does look handsome and charming

but apparently this one super hero is actually a gay

He has a love relationship with Hulkling

which is his teammate at Young Avengers

If you want to know the romance of these two superheroes

You can browse by yourself, because I myself am not brave enough to see it

Hulkling

Hulkling is a super hero who is also a member of Young Avengers

Hulkling has a similar appearance and strength to the Hulk

but these two superheroes

has no family or love relationship at all

Hulkling is a shape shifter

has the ability to change shape and shape

Hulkling was born with the name Theodore "Teddy" Altman

his parents were aliens

As explained

Hulkling has a love relationship with Wiccan

is his teammate at Young Avengers

This means that Hulkling is gay

This super hero pair is known as

"The most famous gay couple in the Marvel world"

Batwoman

Batman itself first appeared in DC Comics in 1939

Following in the senior's footsteps, Robin appeared a year later

Many controversies arose at that time

many say that Batman and Robin are more than just superhero duos

and they are both gay couples

In 1956, Kate Kane was first introduced as Batwoman

as well as being a "love interest" for Batman

it aims to ward off the controversies

In 2006

Batwoman was reintroduced as a person of Jewish and lesbian descent

DC Comics editorial staff strives to diversify the world of DC comics

and also to be more connected to modern readers

Considering that lately there has been widespread exploitation of similar relationships such as lesbian and gay

Harley Quinn

Maybe many are confused why we put Harley Quinn on the list of superheroes

Harley Quinn itself is indeed a criminal

which is a "sidekick" of Batman's archenemy, Joker

But on several occasions

Harley Quinn has also helped Batman to capture the Joker

In some series like Suicide Squad

Harley and some other super villains instead become the main characters and heroes in the story

This series was taken to the big screen

Return to Harley Quinn

He is one of the most famous comic figures in the world DC

Harley Quinn was originally a psychiatrist at Arkham Asylum

The Joker at that time became his patient

It's not Harley that makes the Joker sane

He was even made crazy by the Joker

Harley Quinn is known to have complicated love relationships with the Joker

At first glance, the Joker only uses Harley and doesn't hesitate to kill him

but on the other hand the Joker sometimes acts like a friend and lover

Harley Quinn is also known to have a love affair with Poison Ivy

this makes him one of the bisexual characters in the comic

Mystique

Mystique's iconic appearance that has blue skin and yellow eyes

especially after the wide screen version by beautiful actress Jennifer Lawrence

make this super hero (or super villain) easy to recognize

The initial member of X-men has the shape shifter capability

make it can turn into anyone

Mystique is a transgender because of his abilities

He is a lesbian, together with his partner Destiny (Irene Adler)

Mystique even adopted a child who was also a mutant, Rogue

That was the five super pagans who turned out to be LGBT members as well

sorry if there is one that you like or your super hero

Don't forget to subscribe to the OmLamis channel

to get a video update about the next unique cool movie

For more infomation >> YOUNG AVENGERS ?? Top 5 Famous Superheroes Turned Out To Be LGBT - Duration: 6:51.

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2 mẫu máy câu YOLO giá rẻ - Duration: 5:03.

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